Rules and triggers exist in a 3 level hierarchy:
 
                        FIELD LEVEL
                             |
                             |
                             |
                        TABLE LEVEL
                             |
                             |
                             |
                       PROGRAM LEVEL

Almost all validations will be specified at table level. Field level validations apply everywhere a field is used so you must be careful that the rule is truly a "global" rule to an application. (Refer to Field versus Table Level Rules.)
Also See
Rule Concepts
Understanding Rule Sequence
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